W. Brostow (a), M. Keselman (a), I. M.-Harpaz (b), M. Narkis (b) and R. Peirce(a)

(a) Laboratory of Advanced Polymers and Optimized Materials (LAPOM), Department of Materials Science, University of North Texas, Denton, TX 76203-5310, USA; Denton, TX 76203, USA
(b) Department of Chemical Engineering, Technion, Israel Institute of Technology, Haifa 32000, Israel

ABSTRACT

Friction and wear resistance are two vital tribological properties of polymer-based materials but optimization of both is rarely attempted. We have investigated blends of 70 wt% poly(vinylidene fluoride) (PVDF) + 30% ultra high molecular weight polyethylene, the latter either unirradiated or else g-irradiated. Each sample contained varying amounts of carbon black (CB) and also had a varied degree of crosslinking and irradiation dose. We have determined static and dynamic friction, scratch resistance, and sliding wear in multiple scratching tests. Effects of the irradiation dose and CB concentration have been quantified. The electric conductivity threshold is reflected in a drop of static friction; formation of a continuous phase of the lubricant affects tribology as well as electrical properties-both for irradiated and for un-irradiated samples. The scratch resistance as represented by the residual (healing) depth is affected by crosslinking, by the stage at which irradiation is applied (before or after blending) and by CB addition. Crosslinking by moderate amounts of irradiation provides shallower residual depths while higher doses cause adverse results. Similarly, the CB lubricant can either improve or worsen the scratch resistance. A combination of both approaches produces either better or else worse results than crosslinking alone. Lower friction seems accompanied by higher scratch resistance. A combination of a specific irradiation dose and an optimized CB concentration lowers the sliding wear significantly. Strain hardening in sliding wear determination takes place for all materials studied, irrespective of the extent or radiation-induced crosslinking and of the presence and concentration of carbon black.